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The new experimental data for flames with equivalence ratios of 0.9, 1.0, and 1.2 were used to validate and rank the performance of four contemporary detailed kinetic models.
The profiles in the flame inhibited by HFP are compared to previously published data for flames containing CHF3 and CH2F2 under the same conditions of stoichiometry and flux of fluorine atoms.
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A one-dimensional steady-state theory reasonably correlates the data for flame heat flux and flame length.
The inputs for this model are the initial conditions of the mixture and experimental data for flame radii.
Then, for one-step chemistry calibrated to represent an acetylene/air mixture we simulate the interaction of a shock wave with an expanding flame front, and compare results with 2D simulation (2D-sim) data for flame brush formation and ensuing deflagration-to-detonation transitions (DDT).
The self-absorption correction method of Snelling et al. [D.R. Snelling, K.A. Thomson, G.J. Smallwood, Ö.L. Gülder, E.J. Weckman, R.A. Fraser, AIAA J. 40 9) (2002) 1789 1795] is effective in recovering accurate soot temperature and volume fraction distributions from noise-free emission data even for flames with optical thickness as large as 5.
Measured temperature gradient data for laminar flames differ from that of the unstretched laminar flame calculation, especially in the oxidation layer.
Detailed soot modeling using recently developed PAH chemistry and surface reaction mechanism was performed and the results were compared with experimental data for ethylene flames, focusing on the effects of strain rates.
The present work reports new experimental data for premixed flames of nitromethane, CH3NO2, at atmospheric pressure, and an evaluation of two contemporary kinetic mechanisms based on these new flame studies as well as previously published experimental data on laminar burning velocity and ignition.
Alongside the blow-off data for lifted flame regimes, this enables hydrogen lifted flames to be fully characterised.
Although the hazards of aerosol fires and explosions have been studied for decades the data for aerosol flame propagation is still scarce.
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