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(b) Cross section of a cylindrical micelle.
(c) Depiction of a branched cylindrical micelle.
As the symmetry of these worm-like micelles matches the symmetry of the tubes, adsorbed molecules self-assemble into a cylindrical micelle that encapsulates the tube (Fig. 4c).
The critical difference between encapsulation by a cylindrical micelle and the Langmuir-type monolayer is that the adsorbed micelle forms cooperatively.
We obtained individual nanotubes, each encased in a cylindrical micelle, by ultrasonically agitating an aqueous dispersion of raw single-walled carbon nanotubes in sodium dodecyl sulfate and then centrifuging to remove tube bundles, ropes, and residual catalyst.
Open image in new window Fig. 4 Snapshots of the three structures amphiphilic molecules can form on CNTs: a Langmuir-type layer, b adsorbed spherical micelles and c encapsulation by a cylindrical micelle.
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PEDOT nanoparticles were prepared by reverse cylindrical micelle-mediated interfacial polymerization, according to the method reported elsewhere [8].
P123 forms cylindrical micelles in brine to give high viscosity.
This phase was composed of infinite cylindrical micelles similar to Cd II) carboxylates.
This suggests that the hydrolyzed precursor may orient in a head-on manner with respect to the cylindrical micelles.
The spherical micelles observed at low concentration turn into small cylindrical micelles as the concentration increases.
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