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Thus, upon refolding, intramolecular ligation delivers a cyclic species.
In order to clarify the effect of cyclic species on the measured MWD, a model of the SEC separation of step-growth polymers with cyclic species was developed.
The application of MALDI-TOF-MS showed thermo-mechanicalnical degradation primarily affected initially predominant cyclic species.
Dissociation followed by re-association leads to the formation of a blend of various macromolecular topologies, where the cyclic species make up a significant fraction.
The results from the model are used to develop methods for estimating the MWD of the linear polymer and to determine the weight fraction of cyclic species.
GC/EI-MS and GC/CI-MS spectra were obtained for all of the cyclic species from the tetramer to the nonamer inclusive.
Similar(48)
In the synthesis, cyclic and non-cyclic species were obtained as major and minor fractions, respectively.
These complexes were isolated as mono-, di- and polymeric or cyclic supramolecular species.
In contrast, the minor fuel radical CH3OCH2OĊH2 can go through the O2 addition and the subsequent isomerization steps, as confirmed by the detection of cyclic ether species.
We were able to synthesise unusually stable cyclic sulfonium species and to employ these in a novel bioconjugation that is complementary to current dehydroalanine-based technologies for substrates for which dehydroalanine formation is not facile.
Indeed, only genes in cluster C, whose expression profiles depend mainly on stage VIII gonads (a stage specific to highly cyclic fish species with no equivalent in mice), and in cluster I, which do not show important changes in expression during testis development, were found to exhibit low correlated expression with their mouse orthologs.
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