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In this experiment, after completion of every reduction cycle, the catalyst was collected by centrifugation, dried and used for the next cycle of reduction.
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XPS survey spectra of Al2O3@Ag7,8 before reaction (black), after the first (red) and the third (green) cycles of reduction reactions.
The XRD of samples indicates that the formation of crystalline nickel particles occurs after 2 cycles of reduction.
b Conversion of the above dyes in 10 successive cycles of reduction and magnetic separation with HNTs@Fe3O4@Au-Ni nanocatalyst.
These oxygen carriers were tested over many such cycles of reduction and oxidation.
UV-vis spectra for the reduction of 4-np as a function of time, with SiO2@Ag7,8 (A1-A3), TiO2@Ag7,8 (B1-B3), and Fe2O3 @Ag7,8 (C1-C3). 1, 2, and 3 refer to the first, second, and third cycles of reduction.
The rates of attrition of batches of these particles whilst they were being fluidised and subjected to successive cycles of reduction and oxidation were determined by measuring the rate of production of fine particles elutriated from the bed, as well as progressive changes in the distribution of particle sizes retained in the bed.
For the full length peptide simulation, and as the peptide assumed its persistent compact (helical) conformation, two cycles of reduction of the number of waters were undertaken.
It catalyzes thiol-disulfide oxidation, reduction and isomerisation, this latter occurring directly by intramolecular disulfide rearrangement or through cycles of reduction and oxidation [ 6].
The need of pretreatment of the PB film by conditioning cycles of reduction and oxidation before use for the first time is in agreement with earlier findings [ 21].
Thus, transient cycles of reduction may be helpful in periodically purging the ER of recalcitrant misfolded proteins, while maintaining ER redox at levels optimized for oxidative folding most of the time.
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