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Compared to the anodic peak current of bare electrode which is 1.48 μA, the anodic peak current of modified GCE is at least two times greater.
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The peak currents of modified electrodes are considerably increased in the order of rGO/GC < bare GC < CNT/GC.
The Fc-peptides previously adsorbed on the ZrO2 film modified electrode to saturation can be replaced by the non-electroactive P-peptides by competing the binding sites on ZrO2, resulting in a decrease of peak current of Fc-peptide/ZrO2 Fc-peptide/ZrO2ode.
As can be seen from Fig. 8a c (magnification at low concentration) by increasing the concentration of CySH, the anodic peak current of the modified electrode is increased while its cathodic peak current decreased, indicating a typical electrocatalytic oxidation process (EC′).
As illustrated in Fig. 8a (magnification in Fig. 8a), when the concentration of CySH is enhanced, the anodic peak current of the modified electrode increases, whereas its cathodic peak current diminishes, indicating a typical electrocatalytic oxidation process (EC′).
Second, application of SFCL on each types of HVDC system and comparative study of modified fault current characteristics were analyzed.
It was found that the peak currents of the modified electrode for Pb2+ ions were at maximum value in acetate buffer of pH 4.0.
It was found that the peak currents of the modified electrode for Hg2 + ions were at a maximum value in phosphate buffer of pH 4.5.
It was found that the peak currents of the modified electrode for Hg2+ ions were at maximum value in acetate buffer.
Under the optimized condition, the response peak currents of the modified electrodes were linear over ranges from 2.5 to 200 μM for HQ and from 2 to 400 μM for CT.
Also the results of modified electrodes show that j does not decrease, but increases with time, and compare to CPE the current densities of HER on modified electrodes are considerably greater.
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