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Thermal stability was investigated by post curing samples at 121 °C and assessing healing performance.
Using Quickstep curing, samples were produced exhibiting comparable interlaminar properties but lower flexural strength as compared to those produced using the autoclave.
After 1 months of water curing, samples have been exposed to different sulfate solutions (Na2SO4 and MgSO4) and temperatures (5 and 20 °C) for a period of 6 months.
At the end of the curing, samples are taken from different heights of the columns, and then laboratory tests are conducted to evaluate their physical properties, uniaxial compressive strength (UCS) and saturated hydraulic conductivity.
Table 1 Various cooling conditions for superhydrophobic polymer coatings after curing Samples Crystallization interference methods Thermal conductivity of the mediums[23] Q1 coating Quenched in the air at 20°C K ≈ 0.026 [W/(m K)] Q2 coating Quenched in the mixture of dry ice and ethanol at -60°C K ≈ 0.24 [W/(m K)] Q3 coating Quenched in the pure dry ice at -78.5°C K ≈ 0.099 [W/(m K)].
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Microwave-cured samples show ∼1 order of magnitude higher conductivity than oven-cured samples, whereas the forced thermal gradient results in extreme variations in conductivity.
Consequently, most of the internally cured samples showed higher permeability.
At all ages, internally cured samples experienced relatively high internal RH than control samples.
The only difference between control samples and internally cured samples was the presence of saturated MCA.
The RH data of control and internally cured samples (Fig. 11) also reinforces this inference.
The splitting tensile strengths of control and internally cured samples are shown in Fig. 13.
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