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Ice slurry is a suspension of crystallized water based - ice solution with a freezing point depressant like ethylene glycol.
Internally, crystallized water release starts at 170°C, while adsorbed water release starts above 50°C, which is not observed with a pure CuCl2 · 2HСl or Н2 [CuCl4] active phase.
Crystallized water molecules were preserved.
The intense narrow band at around 3,150 cm−1 is a well-known manifestation of a crystallized water, and it is referred to the "collective band of ice" (Icol) [ 13].
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Many hydrogen bonds of the O H⋯O type are also present in the crystal structure of 1 and assemble the polymeric chains and the co-crystallized water molecules into a 3D architecture.
Non-covalent interactions i.e. hydrogen bonds are present in the crystal structure of 1 and assemble the binuclear units and the co-crystallized water and piperazine molecules into a 3D architecture.
The crystal is built up of a complex Cu(pydc)(amp) and three co-crystallized water molecules (Scheme 1).
Thermal methods confirm number of co-crystallized water molecules in polymer.
Hydrogen bond interactions between the co-crystallized water molecules led to formation of six-membered rings with chair conformation.
Hydrogen bond interactions between the co-crystallized water molecules led to the formation of a six-membered ring with the chair conformation.
These results demonstrate that TetHPB molecules allow to construct hydrogen-bonded networks with cavities; co-crystallized water molecules may cooperate in the formation of these extended structures.
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