Exact(1)
The final porosity turns out to be describable by a modified Frenkel's model accounting for the crystallization constraints to the liquid flow.
Similar(59)
They suggested that the crystallization constraint by the added Al2O3 would result in higher activation energy for the crystallization process.
It is shown that, even for an isothermally crystallized sample, the lamellar melting point varies repetitively and systematically with position in the spherulitic texture, being highest for dominant lamellae then progressively decreasing because, it is suggested, of increasing constraints during crystallization.
Digestion of CopA with papain occurs with specific patterns that provide information about protein conformational states in solution, without constraints by crystallization requirements.
Such structural heterogeneity is a challenging issue for crystallographic analysis because of the constraints associated with crystallization, and the potential for selection of a conformation(s) that preferentially crystallizes.
This might be related to the high octene content of the amorphous phase at the relevant crystallization temperature as well as geometrical constraints since ORC crystallization occurs in an already semi-crystalline polymer.
Additional deviation from the Ozawa model observed at the very beginning and the end of crystallization can be attributed to spatial constraints of spherulitic growth.
The Avrami exponent was extremely small for Block 2 and Block 3, which suggested that their crystallization occurred under a high spatial constraint.
Other vapor-diffusion methods such as sitting drop share the same principles here illustrated for the hanging drop method, although they are subject to different, and generally more complex, geometrical constraints that depend on the crystallization chamber design, employment of micro-bridges or glass rods as droplet holders, etc.
Several crystals were obtained from crystallization screens.
The nanoglobular interfaces remain amorphous and appear to act as a kinetic constraint to induce a higher crystallization temperature compared to the melt-spun ribbon.
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