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The 1/1 copolymer of meta-acetoxybenzoic acid and 2,6-acetoxynaphthoic acid (ANA), prepared by constrained thin film polymerization, crystallizes from the liquid crystal state during polymerization as single disclination domains and lamellar single crystals in the thinnest regions.
Some molecules may exist in the liquid crystal state, which is intermediate to the crystalline solid and liquid states.
However, in the crystal state, the normal modes may shift or split due to various interactions.
The given crystal state and refinement parameters are given in Table 1.
Conformation of arylpiperazine derivatives with polymethylene spacer (H-N+(CH2)nN-Y) in the crystal state (n=3 and 4).
TL-NLC was characterized for particle size, drug entrapment efficiency, crystal state, surface morphology and drug release.
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Organic nanocrystals show unique physicochemical properties different from those of the molecular and bulk crystal states [12 15].
However, m-LLDPE/LDPE blends are immiscible in both melt and crystal states.
Various types of hydrogen bonds of water are detected clearly in the liquid, glass, and crystal states.
The transition mechanism of these functional polymers is the transfer between the amorphous and crystal states of the PEG.
These differences might be a reflection of the different conformations proteins adopt in the dynamic (i.e., solution) versus static (i.e., crystal) states, as both Met483A (located in the linker region between the CaM binding and autoinhibitory domain) and Met166B (located on CNB C-terminal) reside in flexible regions of the protein based on the crystal structure.
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