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The scientific community is manifesting a high research interest on spin crossover compounds and their recently synthesized nanoparticles, due to their various appealing properties, such as the bistability between a diamagnetic low spin state and a paramagnetic high spin state (HS), inter-switchable by temperature or pressure changes, light irradiation or magnetic field.
Therefore, experimental and theoretical studies of spin crossover compounds concern the influence of the pressure on the thermal hysteresis are important.
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As the ligand system plays the most important role in the behaviour of the spin-transition of iron II) spin-crossover compounds a series of eight new mainly bridging di-tetrazole ligands were synthesised and produced new insights into spacer modifications as well as geometric prerequisites of the ligand and their impact on spin-crossover behaviour.
Spin-crossover compounds are a new branch of multifunctional molecule-based magnetic materials.
The main experimental observations on the size reduction effects in spin-crossover compounds are overviewed in paper [19].
The complexity of structure of spin-crossover compounds lead to the appearance of a lot of models for describing the behavior of the main characteristics of these materials.
Thus the theory of phase transformations in spin-crossover compounds should be based at least on two order coupled parameters reflecting its magnetic and mechanical nature [27].
The applied pressure increases the energy gap between spin states and leads to the special feature of spin-crossover compounds that lies in the shifting of transition temperatures toward its room values.
From a point of view of designing new IT devices based on spin-crossover compounds and their practical application, the hysteretic behavior at room temperature is a very important feature.
Within the family of α,ω-bis tetrazol-1-yl)alkanes,ω-bis tetrazol-1-yls and their respective iron(II) spin-crossover compounds were synthesized and structurally and spectroscopically characterized in the past.
14 Therefore, the title complex is another example for spin-crossover compounds with per se flexible ligands that yield an abrupt spin transition-behavior, which is mainly due to packing effects rather than to the stiffness of the ligand itself.
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