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The interfacial tension γ was determined at the critical composition for three temperatures by means of a spinning drop tensiometer.
The critical composition for full co-continuity is found to increase with increasing interfacial tension, narrowing the composition range.
The difference between the composition at elution and the true critical composition for a variety of polymethacrylates and for polyethyleneglycol was found to be only between 0.2 and 5%.
Below 116 °C, G decreases with increasing PEB content in the blend, implying primarily the composition effect on materials transport; whereas at above 116 °C, G shows a minimum at about the critical composition for LLPS, implying the influence of the LLPS.
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Critical compositions for the appearance of these thermal transitions were determined for each series of the diblock copolymers.
In the presence of Li+ and Cs+, both of which are relatively unfavorable for the gel collapse, however, the gel markedly deswelled in an ethanol composition that is lower than the critical compositions for the respective single counterion systems.
The critical composition of carbohydrate segment in copolymers for enhanced gene delivery and low toxicity was determined and an increase in carbohydrate residues in copolymers resulted in a decrease in transfection efficiencies of these polymers.
The critical composition difference for blends of amorphous copolymers of about 9 wt% also applied to blends of semicrystalline copolymers.
We found that the recognition ability had the maximum around Ͽ0.75 and there was the critical composition at Ͽ= 1.0 for which the recognition was drastically reduced.
Phase diagrams (cloud point curves, critical points, tie lines for constant critical composition) and interfacial tensions as a function of temperature were measured for solutions of two random copolymers: poly(dimethylsiloxane-ran-methylphenylsiloxane) [I] and poly styrene-ran-acrylonitrile) [II].
The associated co-continuous morphology is only preserved in the actual critical compositions whereas for off-critical compositions it rapidly breaks up into spherical particles.
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