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After baseline correction, spectra were expressed as the Mean Residue Ellipticity MRE.
23 24 Following manual first and second order phase correction, spectra were analysed using a non-linear least squares algorithm (AMARES).
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The most challenging aspect of data analysis is raw data processing, which involves data conversion, baseline correction, spectrum deconvolution, peak detection and integration, chromatogram alignment, normalization, and compound identification and quantification (Figure 1D).
Appropriate blanks were subtracted to obtain the corrected spectra and corrections owing to dilution were made to the observed fluorescence intensities.
The correction to spectra prior to the joint inversion was based on the equation for moment by Aki and Richards (1980, p. 116).
After baseline correction, the spectra were expressed as the Mean Residue Ellipticity MRE.
In the second correction method, reflectance spectra recorded by NIRS3 are corrected based on the FT-IR spectrum of the Allende sample.
Then Doppler signal was processed by tracking filter, frequency spectrum refinement and frequency spectrum correction algorithm.
The calibration models for prediction of DE obtained on extended inverse signal correction (EISC -treated spEISC -treatedthree spectrascofic methods yielded models with cross-valldathreerediction errorspectroscopictween 1.1%p and 1.6%p DE and correlation coefficients of 0.99.
Device software provided the correction of the spectra by taking into account a sensitivity curve in consideration of the spectral sensitivity of a multiplier photocell used in a fluorometer.
The mass list was generated by the SNAP peak detection algorithm using a signal-to-noise threshold of four following baseline correction of the spectra.
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