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Furthermore, the folded core models are compared to a honeycomb core model with the same density and height.
It is a new type of micro-fracture core model with the fracture apertures in the range of 1 50 μm.
Kinetic analysis of the results indicates that the dissolution of limestone is according to the shrinking core model with surface control, i.e. 1−(1−3)1/3 = kt.
To achieve this goal, it is assumed that pyrolysis begins soon after the surface of the particle has reached a certain pyrolysis temperature, and proceeds according to a shrinking (unreacted) core model with an infinitesimal reaction front.
It is shown that, in the leaching process, particles follow the shrinking core model with respect to formation of unreacted core that is encapsulated by a leached, porous, layer.
The sorbent decomposition is considered to follow a shrinking core model with a changing pore size distribution in every shell and the sulphation takes place on the porous surface of CaO generated during sorbent calcination.
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It is found that the folded core models with curved fold lines exhibit the best mechanical performances in compression and shear while the multiple layered models outperform the other folded core models in bending.
In this work, we propose and assess a Geometric Multiscale approach on MSR, addressing the core modelling with a 3-D MP approach and the remaining part of the system – e.g., the cooling loop – with simplified 0-D models based on Ordinary Differential Equations (ODE).
The following ten items were included in the apparatus: (1) microscope constant-flux pump; (2) control apparatus of gas mass flow; (3) high-pressure gas tank; (4) storage tank of fluid agent; (5) pressure sensor; (6) two core models with different permeability; (7) back-pressure control device; (8) temperature control box; (9) separation apparatus; and (10) measurement apparatus.
We demonstrated the adequacy of the core models with partial autocorrelation function plots of the residuals in the previous 2 days, all within |0.1| [Supplemental Material, Figure 1 (available online at http://www.ehponline.org/members/2008/11257/suppl.pdf)].
As discussed in section 9, below, models of E4(N2) constructed by placing N2 and two protons on the doubly reduced FeMo-co core modeled with its resting-state structure provide a convincing illustration of this mechanism (and other insights, as well).
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