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The structures represent snapshots of the enzyme trapped at different stages of the catalytic cycle and show how substrate binding triggers a switch in the coordination state of an active site Mn II) between six- and five-coordinate species.
The chemical coordination state was determined from diffuse reflectance spectroscopy (DRS) measurements.
The evolution of the coordination state of Al and P during the crystallization was monitored.
Starting the aqueous structure in a higher coordination state is a test of whether the lower coordination state observed (i.e., CN=7) can be reproduced or whether a local minimum would be found.
Both CO and NO are adsorbed onto Fe2+ cations and have different sensitivities to their location and/or coordination state.
Energy minimization for this model within a self-consistent reaction field could be performed to test whether long-range solvation could stabilize the higher coordination state.
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The importance of the low coordination states and effects of symmetry disturbance of crystal and ligand fields are emphasized.
Two different types of surface Ti+3-species have been identified on the catalyst surface depending on the different vacant coordination states of surface titanium species.
In other words, the luminescent efficiency of the Ce3+ centers in amorphous materials strongly depends on the various local coordination states.
The silicate melts generated by the partial melting of MORBs might thus undergo a structural transformation involving possible densification changes related to Si-O coordination states at depths of around ~2690 km, which is clearly shallower than the CMB.
The absorptions in the range 250 to 350 nm were assigned to O2 → Zr4+ charge transfer transitions with Zr in low coordination states (possibly six) either isolated or present in small ZrxOy clusters [10].
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com