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Pt(N(H 6-Medpa)G adducts form syn and anti rotamers witH 6-Medpanine O6 and the central N–H of N(H)6-Medpa on the same or opposite side of the coordination plane, respectively.
To accommodate the desired migratory insertion, pinBH adds to Im0 in a direction more perpendicular (rather than parallel, as previously examined) to the coordination plane encompassing Rh.
The proximity of the tert-butyl substituents to the nitrogen donor in 1 and 4 is responsible for the positioning of the metal centre below the coordination plane in a half-sandwich conformation (see Figure S2 in the Supporting Information).
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Figure 5 represents some spinodal curves and its projections on coordination planes n H −T, n H −p and p−T for different values of intermolecular interaction parameters J 0. Fig. 5 (Color online) p−T−n H spinodal curves and its projections on coordination planes.
In 2 the dysprosium centers were constructed into one dimensional chain by OCO bridges from pydc ligand bridges and these chains were linked by oxalate bridges to form sheets and different sheets were connected by copper coordination planes.
Based on our parameters, the corresponding 3D plots are summarized in Fig. 3. Fig. 3 (Color online) The distortion ξ as a function of temperature T and HS fraction n H and its projections on coordination planes for different values of pressure p. The pressure is increasing as is shown on the right at each figure.
Molecules pack into dimers [for α- 1, Pd···Pd = 3.7903(10) Å; for α- 2, Pt···Pt = 3.8237(4) Å] with the coordination planes parallel to each other and with perpendicular separations of the least-squares planes of 3.625(2) and 3.6815(14) Å and shifts of 1.182 2) and 1.120 2) Å for α- 1 and α- 2, respectively.
The X-ray diffraction study of [Cu2L CF3SO3 4] clarified that the molecular structure was topologically spiro but the two coordination basal planes were not orthogonal with the dihedral angle of 49.8(1)°.
In complex 3, two bridging 4,4′-bipy ligands and two terminal ipH ligands confine the CuII center in a square plane coordination geometry.
As a consequence, a distinguishing feature of plant mitosis is the coordination of division plane and spindle assembly (Brown and Lemmon 2001, 2007; Wasteneys 2002).
It is possible that lateral plane coordination represents a more advanced stage of recovery, which is dependent on brainstem-spinal cord connections and cannot occur in animals with very severe SCI.
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