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Judicious application of coordination ligands is a critical success factor in the design of effective anti-tumor compounds.
Most stable free radicals have a sophisticated chemistry allowing the design of multi-site coordination ligands whose metal complexes are oligonuclear with a fairly high ground spin state.
We have synthesized a series of novel titanocene complexes with liquid-crystalline (LC) groups as coordination ligands, with the ultimate aim of developing LC catalytic species available for anisotropic polymerizations of acetylenes.
The reactive periphery of the chlorocyclophosphazenes allows their ready elaboration into a variety of multi-site coordination ligands such as pyrazolylcyclophosphazenes, cyclophosphazene hydrazides, pyridyloxycyclophosphazenes, pyridylaminocyclophosphazenes, phosphine-containing cyclophosphazenes, etc.
The observed contact surface area (31 35 Å) between the side chain aspartate oxygen atom (Oδ2) and histidine (Nε2) implies that the metal coordination ligands in the exposed region may perhaps tune the redox potential (Fig 3, 4).
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As for the additive of LiBH4 which acts as the second coordination ligand (BH4−), from the kinetics viewpoint, its increased concentration can also speed up the stripping process at electrode surface.
DGM complexion is thermodynamically and kinetically favorable; LiBH4 additive acts as the second coordination ligand (BH4−) and its increased concentration can also speed up the stripping kinetics at electrode surface.
Cytotoxic responses are influenced by both the identity of the metal and the properties of its coordination ligand, with clear associations between structural similarities and cytotoxicity.
The coordination ligand (L) thiourea complexing agent played a key role in the interface reaction between the inner Cu core and the outer Sn shell and also significantly impacted the surface morphology of the outer coating layer.
The bidentate ferrocenyl sandwich molecule N,N′-bis-3-pyridylmethyl-1,1′-ferrocenedicarboxamide (3-BPMFA) has been employed as an organometallic coordination ligand in reaction with CdBr2 to construct heterobimetallic architectures.
In this synthesis, the starting materials can dissolve in DMF and DMF can partially decompose into dimethylamine, which is a good coordination ligand with N-chelation.
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