Exact(26)
The inter-chain C H···Cl hydrogen bonds between the pyridine rings and the coordinated chloride anions extend these 1-D coordination frameworks to result in a novel 2-D supramolecular architecture, and there exist significant edge-to-edge π π stacking interactions between the inter-chain neighboring pyridyl rings of the ligand, which may further stabilize this structure.
The stability and rigidity of both coordination frameworks are mainly supported dominantly by AgI ⋯ AgI interactions.
The 3D architectures and degree of interpenetration of these coordination frameworks were significantly affected by silver(I) cyanide species.
On-site recrystallization has been proposed as a straightforward method to produce large 2-D nanosheets of crystalline surface-anchored metal organic coordination frameworks (SURMOF).
The luminescent properties of 1 and 2 have been investigated in the solid state at room temperature, indicating structure-dependent photoluminescent properties of the coordination frameworks.
Researchers have worked to create a diverse range of coordination frameworks and have raised the structural chemistry to a mature level.
Similar(34)
Compound 1 exhibits a 3D coordination framework containing carboxylate- and hydroxo-bridged chains.
We illustrate and analyze the coordination framework using three simulated scenarios.
Compound [Zn2 oba 2 bpe)] · 2DMF · 4H2O exhibits a three-dimensional coordination framework that is comprised of heteroorganic bridges.
These clusters are connected through the coordination of carboxylate oxygen atoms of TMA ligands to form a 3D coordination framework.
Complex 1 possesses an interesting 3D coordination framework with a rarely binodal (4,4 -connected frl topological structure.
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