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As for coordination entity 3, hydrogen bonding and π⋯π stacking link the molecules in a three dimensional manner.
The corresponding crystal structures indicate the formation of supramolecular architectures generated by offset π⋯π stacking between pyrene fragments and strong C H⋯π interactions in coordination entity 1.
Photophysical studies of the ligand and corresponding coordination entities show a monomer type pyrene emission and a higher fluorescence quantum yield for the zinc coordination entity 1 as compared with copper 2 and rhenium 3 coordination entities.
For the cationic coordination entity 2, the crystal packing reveals the presence of C H⋯F and C H⋯π interactions and numerous C H⋯π contacts interconnecting the molecules into a 3D network.
Our requirement for intelligent interaction with the environment has led to the emergence of Wireless Sensor and Actor Networks (WSANs), where a group of sensors, actors, and a central coordination entity (sink) linked by wireless medium perform distributed sensing and acting tasks.
For these reasons, adaptations may be triggered at coordination level, issuing reconfigurations to such a coordination entity.
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Zinc II) and copper(I) coordination entities have also been studied through isothermal titration calorimetry, which indicate a strong binding and a different stoichiometry for both coordination entities.
Ligand L, as well as two neutral and one monocationic coordination entities, respectively formulated as [ZnLCl2] 1, [ReLCl(CO 3] 3 and [CuL2](BF4) 2, have been crystallized and analyzed by single crystal X-ray diffraction analysis.
In 1, the adjacent CdII centers are bridged by a pair of μ1,3-SCN− anions to form a 1-D array, whereas in 2, the monomeric CoII coordination entities are hydrogen-bonded into a novel 3-D architecture in which the thiocyanate ions take the only N-binding mode.
Spectral techniques (MS, infrared, 1H NMR, 13C NMR, electronic and EPR), physiochemical measurements (elemental analysis, molar conductance and magnetic susceptibility), electrochemistry (cyclic voltammetry) and classical mechanics (molecular modeling) were employed for structural elucidation of Co II) and Mn II) coordination entities having N2O4 chromophore.
Other syndromes of childhood developmental disabilities include reading disorder/dyslexia, non-verbal learning disorder, dyscalculia, and disorders of motor coordination; entities that often overlap and coincide.
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