Sentence examples for coordination chain from inspiring English sources

In the structure of 1, the Mn II) ions are octahedral coordinated and further bridged by L− ligands, forming a rigid 1D ribbon coordination chain.

The crystal structure of 1 reveals that the ligand molecules bridge the tetrahedral ZnII centers (ZnN2Cl2) in the unprecedented transoid conformation, forming a one-dimensional zigzag coordination chain.

Single-crystal X-ray diffraction indicates that complex 1 features a 1D coordination chain and further forms a 2D supramolecular network extended via π⋯π stacking interactions.

Complex 1 is a 1D coordination chain of Fe(H2O 2 units connected by μ-O,O″ squarate dianions with monocoordinated bpp ligands dangling from the polymer.

In complex 1, Mn II) cation adopts a novel seven-coordinate distorted pentagonal bipyramid polyhedron, while in complex 2, four different Mn II) coordination environments are observed and form a novel 1-D zigzag coordination chain.

Under the tuning effect of anions with different coordination capacities and steric bulk, the semi-rigid ligand L exhibits versatile μ2-, μ3- and μ4-bridging modes with the N-oxide and/or sulfonyl O atoms functioning as bonding sites to form a coordination chain structure in complex 1, isostructural nets in 2 4, and a three-dimensional framework in 5.

Reaction with Cu OAc 2 in a 2 1 stoichiometry afforded the one-dimensional coordination chain-like polymer [Cu HL1 2]n 3 for which the solid state structure has been determined.

In complex 2, 1D zigzag coordination chains were generated and further linked through hydrogen bonds to form a 2D structure.

The inter-chain π π stacking interactions between neighboring phenyl rings in Eu2 chains extend the 1D coordination chains to construct a novel 2D supramolecular architecture, which further stabilizes this structure.

The overall structure of 1 consists of 1D helical coordination chains which are further extended into a 3D supramolecular architecture via π π stacking and CH⋯N hydrogen bonding interactions.

In the isomorphous compounds 1 and 2, octahedrally coordinated metal ions are linked by the (μ-EO-N3 2 (EO = end-on) double bridges to give dinuclear motifs, which are linked by the zwitterionic dicarboxylate ligands to produce one-dimensional (1D) coordination chains.