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This observation confirms the proposed decomposition mechanism concerning increasing amount of [FeIII(NH2CH2CH3 2 μ-NC 2CoII CN 3] at higher temperature (see step III in Scheme 1 and Table 4) and it indicates that CoII CN FeIII is the most probable coordination bridge in [FeIII(NH2CH2CH3 2 μ-NC 2CoII CN 3].
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As noted with other dinuclear metalloenzymes (38), changes in the coordination bridges and lengths may represent the flexibility of the metal site to coordinate different species along the reaction coordinate.
The CCSP could be expanded to include management research and coordination to bridge the gap between resource management needs and scientific research priorities.
While the electrostatic reaches into the long range, the partial charges also contribute to the molecular recognition in the short range where they are the driving forces of polar interactions (hydrogen bonding and salt bridges) determining the specificity of recognition as well as the coordination of bridging waters between the receptor and ligand.
The complex (6) is a coordination polymer bridged by bromide anions.
Both 1 and 2 are zigzag coordination polymers bridged by weak Ag⋯Ag, Ag⋯S or Ag⋯NC CH3 interactions to form double stranded coordination polymers.
The dimeric Cu-pydc coordination framework bridged by a bpo spacer in 1 is hydrogen-bonded to four others to result in a two-dimensional (2-D) sheet array.
The triplesalen ligand (talent-Bu2)6− provides three salen-like coordination environments bridged in a meta-phenylene arrangement by a phloroglucinol backbone.
While in compound 3, H3L2 ligand exhibits u6 η1: η1: η2: η1: η1: η2 coordination mode to bridge six Mn (II) ions, leading to a 3D open framework.
The structures of the compounds are all based on an infinite 1D chain constructed by four-coordinate metal ions and dppeO2 ligands adopting the trans bridging coordination fashion.
The youthful demonstrators who make up these coordination committees have bridged divides of sect, religion and class to try to formulate a leadership.
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