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Structural analyses of these compounds reveal that the cationic moiety is a monomeric complex in which the metal is coordinated by five aqua ligands and one carboxylato O-atom from the 5-nitrosalicylato ligand, forming a slightly distorted octahedron.
It was found by X-ray diffraction analysis that cadmium is coordinated by five oxygen and one sulfur donor atoms provided by two thioglycolate molecules and one water molecule.
Compound 3 is composed of 〈0 0 1〉 and 〈0 0 2〉 manganese(II) phosphonate layers, in which each metal ion is octahedrally coordinated by five phosphonate oxygens from four ligands and an aqua ligand.
On average, Y ions in α-Al2O3 grain boundaries are coordinated by four oxygens, at a distance of 2.30 Å, which corresponds nearly to the Y O bond length in cubic Y2O3, and Zr ions are coordinated by five oxygens at a distance of 2.14 Å, which is approximately the same as the average Zr–O bond length in monoclinic ZrO2.
Each of the cadmium center is six coordinated by five bromide and one benzyadeninium cation (BAH+) (Figure 9).
The three Ca2+ ions bound at the cavity formed by the top loops are coordinated by five aspartate and one serine side chains, as well as by three backbone carbonyl groups (Figure 5A; the Ca2+-binding sites are numbered 1 3 as is common for C2 domains [33]).
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This coordination complex, a "typical" Werner-type complex, consists of a central cobalt atom coordinated by six ammine ligands orthogonal to each other and three chloride counteranions.
M2 is coordinated by six oxygen atoms.
The latter is uniquely coordinated by three carbonmonoxide (CO) and two cyanide (CN−) ligands.
The central domain contains a [Fe4S4] cluster coordinated by four conserved cysteine residues.
Co is coordinated by six IMI molecules and forms an octahedral structure.
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