Ethylene glycol (EG) is an optimal solvent that possesses good coordinating ability, and serves as a ligand to form coordination complexes with Co II) and Mn II) cations upon heating.
The coordinating ability of Ag(I) ions enables further attachment of the above-mentioned carboxylic acids onto the surface (Material D) and other neutral antimicrobials (Material E).
This difference in coordinating ability is clearly correlated with the observation that non-dithiocarbamate structures are more likely to form high-dimensional supramolecular architectures.
It was shown that the ionic liquids anions have coordinating ability and the basicity order found was: NTf2− < OTf− < BF4−, in agreement with previous findings.
It is showed that the stronger coordinate ability of bidentate APO ligands facilitates the stability of the complex monomer during polymerization, and their beetling coordinate sites and adjustable structure efficiently reduce the steric effect of bulky EuM.
It appears that the nature of the polymer is important in determining the level of ionic conductivity, possibly due to differences in polymer coordinating ability or differences in Tg.
Not only the rigidity of the organic ligand and complexes structures, but also the coordinating ability between rare earth ions and ligand played a crucial role in the stability of the complexes.
In this context, we fine tuned the coordinating ability of these ligands by incorporating pendant hemi-labile functionalities on phosphorus centers which resulted in the isolation of several interesting molecules.
As-formed nanosheets will further aggregate into hierarchical spheres at appropriate conditions, driven by the minimization of interfacial energy27,28,29, The different properties of the used organic solvents, such as polarity, viscosity and coordinating ability may be significant in the shape control of the precursor.
Especially, effects of donor atoms O/S on adsorption were investigated, and the outcomes indicate that the difference in coordinating ability between the donor atoms is weakened in large conjugated systems, and the related functional groups with originally very strong coordination abilities may not be the best choice for the application in selective adsorption of uranium and also other metals.
