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In addition to the study of the α-motional modes associated with local intra-segmental motions and the onset of cooperative motion, we have also identified and studied a higher order cooperative (normal-mode) motion of extended segments of the carborane siloxane co-polymer chains at elevated temperatures.
Therefore, the motions of the yaw and gripper axis are performed by cooperative motion.
These facts are considered due to that the RAP formation leads to the suppression of cooperative motion for amorphous chains.
Network inhomogeneities and cooperative motion were analyzed at varying the cross-linker concentration and the polymer volume fraction.
To reflect the cooperative motion, T0 was distributed between the T0 of PoCS and that of PS.
The cooperative motion appears at about 50 K below the glass transition temperature, corresponding to the Vogel Fulcher temperature.
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The α relaxation involves long-range, generalized and highly cooperative motions of the main chain.
This modification is proportional to length scale variations of molecular cooperative motions at Tg, ξ Tg).
The β′ relaxation corresponds to more or less cooperative motions of main-chain segments.
Notably, these new atomic channels manifest subtle electrostatic environments facilitating cooperative motions of at least two Li atoms.
These facts provide conclusive evidence that cooperative motions of main chain segments are responsible for most of the stress relaxation.
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