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From the narrow distribution of relaxation times and q2-dependence of relaxation rates, it was verified that the relaxation processes concerned in this study were due to the concentration fluctuations caused by cooperative chain diffusion.
Concentration fluctuation and cooperative chain mobility of the hyperbranched poly(ε-caprolactone)s (HPCLs) as well as that of the linear poly(ε-caprolactone) (LPCL) in their concentrated solutions in tetrahydrofuran (Cpolymer=1.0 g/mL) were systematically characterized using photon correlation spectroscopy (PCS).
As a result, cooperative chain mobility of the HPCLs in the concentrated solution state was found to be higher than that of the LPCL, and was enhanced with the shorter linear segments and with the higher relative DBs of the HPCLs.
We further show that the unstable regions are locally stabilized upon binding actin, and that they unfold in multiple overlapping units prior to the molecule's dissociation from actin and cooperative chain separation.
Lattice protein models are simplified instances of the generic class of cooperative chain folding processes, which include the actual folding of biological macromolecules.
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Thus, hierarchical and less cooperative chains often inhibit more complex and promising forms of upgrading.
Regular chain stores must be distinguished from franchises and from voluntary or cooperative chains, in which the retail units preserve their individual ownership.
Chain models with either much weakened local conformational propensities or much weakened favorable nonlocal interactions are significantly less cooperative than chain models with both strong local propensities and strong favorable nonlocal interactions.
Furthermore, through Eachmile Technologies, tFcn has been helping each other establish cooperative supply chain relationships, many of which are involved in FIshery Improvement Projects that will benefit their respective fishers and seafood consumers.
Thus, the determinants for formation of the cooperative side-chain interactions are located mainly in the α-helical domain.
First, there are cooperatively owned organizations, whether controlled formally by their suppliers (as in agricultural cooperatives), by their customers (as in mutual insurance companies or cooperative retail chains), or by their employees (as in some commercial enterprises, such as Avis).
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