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The viscosity of the reaction medium appears to control the polymerization rate and molecular weight distribution.
Consequently, one way to overcome these limitations is to control the polymerization rate of the pyrrole monomers and improve the processibility of CNTs in solution.
Both MGEDBA and RhoBEDBA were efficient RAFT chain transfer agents to control the polymerization of N,N-dimethylacrylamide (DMA).
Reversible addition-fragmentation chain transfer/macromolecular design via interchange of xanthates (RAFT/MADIX) technique was applied to control the polymerization process.
In this work, BPO (benzoyl peroxide)–e−aq and DMA (N,N-dimethyl aniline)–OH were used to control the polymerization position at the water oil interface.
On the other hand, the polymerization mediated by 2 at 80 °C showed a good 'livingness' of polymerization, but 1 had a poor ability to control the polymerization to give poly(St) with a broad polydispersity of 1.52.
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Corresponding 'free' initiators were added into the solutions to control the polymerizations.
It has been established that Cu (II) generated in the atom transfer equilibrium is vital in controlling the polymerization.
The results underscore the importance of the anion in controlling the polymerization of IL monomers.
At [SDS]=2 mM, homogeneous nucleation controls the polymerization kinetics regardless of [C5OH].
GO-T acts as a multifunctional macroalkoxyamine initiating and controlling the polymerization in the presence of monomer.
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