Fig. 1 Compositional dependencies of energetic barriers of local chemical decomposition (a, c) and global phase separation (b, d) for geometrically optimized NFC in As Se (a, b) and As S (c, d) glassy systems (compositional domains of expected optimally constrained phase determined in respect to TM-DSC [5 8] are shadowed).
These images are digitally obtained by an iterative reconstruction process (~15 iterations) that is based on object-support constrained phase recovery, which effectively removes the twin image artifact of in-line holography [ 3, 18, 32].
Three phases were detected for the blends with PEO component >16%, containing one miscible homogenous PBzMA-rich phase, one constrained PEO phase and one crystalline PEO phase.
where m is an integer number and 2πm represents a phase wrapping factor which constrains a phase range [-π ~ + π).
We report observation of the disappearance and recreation of the rigid, or constrained, amorphous phase by sequential thermal annealing.
The axes of reflection symmetry are invariant by the flow, which constrains the phase portrait to look like the one shown in Fig. 4.
The highly packed PFA-C8 phase (higher-ordered phase) constrained the PEG crystallization, whereas the loosely packed PFA-C8 phase (lower-ordered phase) caused a weak restriction in the PEG crystallization to give relatively ordered PEG crystals.
Both are completely valid phasings consistent with the genotype and read data but fragments connecting SNPs 1 and 3 may constrain the phasing solution to be unique.
Conformers representative of the complete pyranose Cremer Pople (Cremer and Pople 1975) conformational space (74 in total) were built using in-house software, which systematically increments θ- and φ-parameters (by 30°) and then performs constrained gas-phase energy minimization (to maintain the pucker) using the UFF force field (Rappe et al. 1992).
%, which considers the rigid crystalline phase, the constrained (semi-rigid) amorphous phase inside the lamellar stacks and the free (mobile) amorphous phase outside the stacks.
