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Based on it, four compounds 2 5 have been designed by modifying the connected bridge between electron-donor (D) and electron-acceptor (A) units.
As a consequence, for this kind of DCBPy emitter, modifying the connected bridge between D and A units is a valid approach to improve their TADF performances.
The calculated normal mode reorganization energy for the non-radiative decay process shows that the λ of compounds 2 5 in the high-frequency region is noticeably reduced compared with compound 1, suggesting that the high-frequency CO stretching vibration is hindered through modifying the connected bridge between D and A units.
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A reasonable elimination of the presence of connected bridges was shown to lead to better predictions in the low moisture content regime.
Besides connecting bridge and ring size, several key parameters essentially influencing on NLO property were highlighted, including M0k, Mkn, ƒ0k × ƒkn and Ne.
In 1788, a wooden drawbridge was built over Rock Creek to connect Bridge Street with M Street NW in Washington.
But, increasingly, they are everywhere, connecting, bridging, even in out-of-the-way tropical towns like this one.
The metal connecting bridges, for example, are sized to be habitable additions to the external space, not just conduits for people.
No connecting bridges.
j/17) Fazekas 2, Connecting bridges.
n/13) Fazekas 2. Connecting bridges between lesions.
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