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The present study investigates the photophysical properties of two highly conjugated pyrene and anthracene derivatives viz (E -4- 2- pyren-1-yl) vinyl) bE -4- 2- pyren-1-yland (E -4- 2- pyren-1-yl9-yl) vinyl) bE -4- 2- pyren-1-ylin thE -4- 2- pyren-1-ylncE -4- 2- pyren-1-yls such as N,N-diethylaniline (DEA) and N,N-diphenylamine (DPA).
It proves that conjugated pyrene plays much less contribution to frontier orbitals than non-conjugated pyrene.
And in contrast, conjugated pyrene substituted PDOF-P and PDAOPF-P show structureless spectra.
In order to explore the influence of non-conjugated and conjugated pyrene on the properties of polymers, four alternating pyrene fluorene linear copolymers, PDOF-PPF, PDAOPF-PPF, PDOF-P and PDAOPF-P (Scheme 1), were designed, synthesized and characterized.
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Another approach with pyrene moieties inserted into the stem of MB was described by Matsumoto et al. [ 90] who incorporated into the MB stem one or two guanosines conjugated with pyrene through C8 alkylamino linkers.
For non-conjugated pyrene substituted PDOF-PPF and PDAOPF-PPF, absorption spectra show sharp peak at about 354 nm, which should be attributed to intramolecular interaction of pyrene and main conjugation.
The design and synthesis of two conjugated pyrene-2,2′-bipyridine linear rods is described.
The excimer emission intensity could be scaled by increasing the number of pyrene monomers conjugated to the 5′ terminal [ 88].
The DFT structures disclose HOMO is localised on pyrazoline donor moiety in conjugated part whereas LUMO is spread over pyrene acceptor unit in non-conjugated part.
A novel cyclodextrin conjugated peptide, 1, having two different fluorophores, coumarin and pyrene, in the side chains has been designed and synthesized.
The alterations in the ratio of fluorescence intensity (I337/ I335) of pyrene with the log (concentration) of FA and RA conjugated DEX copolymers were recorded for finding the CMC [ 6].
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