Sentence examples for conformation scheme from inspiring English sources

It is expected that the first transition state with oxocarbenium character would adopt a H3 half-chair conformation (Scheme 1).

In searching for guests to fill the voluminous (870 Å) cavity of CB[10], we found that tetracationic calixarene 32 forms the CB[10]·1,3- alt- 32 complex in which 32 preferentially assumes the less stable 1,3-alternate conformation (Scheme 3).

As the RVxF motif of PIPs binds in an extended conformation to PP1, [8] we sought to develop D-Pro L-Pro-templated linear peptides and D-Pro L-Dap (L-Dap= L-2,3-diaminopropionic acid) templated disulfide-bridged cyclic peptides to display the RVTF motif in an extended conformation (Scheme S1 and Figure S5).

Therefore, in the WT protein, the active conformation (Cu·Ea1 in Scheme 1) can be obtained only following occupancy of both NMBD and TMBS copper sites.

The above results bring two important questions: (1) whether the macroscopic kinetic laws hold in quasi-static or quasi-equilibrium limit for more complicated reactions schemes despite conformation fluctuations and (2) what kind of deviations one can expect when MM law breaks down.

In such schemes the conformation of the neck linker was mainly thought to affect the nucleotide affinity by triggering rearrangement of the switch loops.

In the absence of ATP, reactions with some substrates did not go to completion, suggesting an equilibrium between different substrate conformations as shown in Scheme 1.

Fig. 1 General scheme for BCL Conf conformation generator.

A notable example of chelation control of conformation was provided by trisaccharide 29 (Scheme 8 ).

Analysis of PSD scores suggests that there is a continuous aspect of protein conformation space, even though various classification schemes are extremely useful.

This would generate a steady sampling of conformations at defined rates at equilibrium (Scheme 1).