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In this study, we focus on the conformation of polymer chains.
In the case of polymer materials, the conformation of polymer chains is strongly connected with their various properties as well as the surface morphology.
Conformation of polymer chains strongly confined in a narrow channel space was studied over a broad range of polymer volume fractions φ using lattice Monte Carlo simulations.
A hypothetic mechanism is assumed to explain the effects of elongation and shear rates on the changes of conformation of polymer chain.
The results obtained from torsional angles studies confirmed the presence of a great number of induced physical defects in the backbone and, hence, a collapsed conformation of polymer chains in methanol.
Combined with the polymer radius of gyration obtained from Dissipative Particle Dynamics simulation, we found that the adsorption amount of polymer is small when conformation of polymer is extended in a solution.
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It was the mutual interactions determined the solubility and conformation of polymers in ILs.
The presented technique was proved to be a convenient and quick method to study the shape and conformation of polymers in solution at high temperature.
The observed change in the force parameters with increasing cation concentrations and valency suggests a collapsed conformation of polymers at O/W interface in the presence of hydrated ionic surface structures due to the strong coulombic attraction between cations and oxygen, leading to bridging of PVA chain segments.
The theory explicitly includes conformations of polymer chains, as well as size, shape, and volume of every molecular species in the system.
The interfacial characteristics could be described well in terms of bimodal conformations of polymer chains, similarly to polymers adsorbed on flat solid surfaces, and in terms of changes in apparent interfacial layer thickness.
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