Sentence examples for configurational control from inspiring English sources
The preparation of a new class of axially chiral NADH models based on configurational control of atropisomeric lactams is described.
The configurational control of this chiral axis is achieved via the presence of a second chirality element installed on the lactam moiety of the reagent 2. Reduction of methyl benzoylformate led to methyl mandelate in 89% yield and 92% e.e.e
The conformational and configurational control of the lactam moiety was successfully achieved affording two conformational diastereoisomers (aS,S -1 aS,S -1,S)-1 in andaRio of 95:5,S -1pectively.
This paper reports the design of a new axially chiral NADH model which relies on the configurational control around the C3-CO chiral axis by means of a chiral relay installed on the cyclic structure.
Reduced flexibility is one feature of configurational restraint in bridged cyclam chelators.
The use of configurational switches to control long-range order in liquid crystalline phases has been discussed elsewhere (section 8.6.3 ), but a similar application in synthetic polymers often furnishes a useful result.
In this study, the active vibration control and configurational optimization of a cylindrical shell are analyzed by using piezoelectric transducers.
The control of the degree of configurational order – through simple heat treatment schedules –, and simultaneous application of stress and magnetic field enabled us to observe a Kauzmann point, that is, the collapse of the entropy difference between a crystalline and a glassy phase.
The overriding theme of the theory is that stimulation is perceived in organized or configurational terms (Gestalt in German means "configuration").
In this work, we demonstrate the configurational and dimensional transformation of Ag nanostructures on sapphire (0001) via the systematic control of deposition thickness in various annealing environments.
Space syntax approach was used to measure four park pathway configurational characteristics, i.e., average depth to gates, average depth to landmarks, control value, and global integration.
