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It offers multiple, concerted, bonding sites for heavy metals and forms a stable metal ligand precipitate.
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The program exhibits good scalability on parallel computers and has been used to study concerted bond-breaking events in the fracture of alumina.
The concerted hydrogen bonding of the N atom of the indole ring of PT3 with Asp887B and Cys1355A found in the modelled complex, which results in an additional hydrogen bond in comparison to the complex with PPT5, could account for the better binding of PPT3.
For the rate constant to be sensitive to the p Ka4 value of the leaving group, the bond forming (associative process) and bond breaking (dissociative process) about Pα must be concerted or dominated by P O bond breaking.
Ligand coupling reactions of sulfoxides, involving concerted intramolecular coupling of two groups bonded to sulfur, occur via a tetrasubstituted sulfurane intermediate with a trigonal pyramidal structure.
There are not even concerted efforts like the savings-bond drives or gasoline rationing that helped to unite the country behind its fighting forces in wars past.
Mechanistic investigations pointed towards a concerted addition of the C H bond across the aryne intermediate, a reaction with little precedent in carbocyclizations.
It can be concluded that the favorable energy path by the kinetic analysis is that the α-H migrates to S firstly; then the β-H migrates to the α-C followed by a concerted C S bond cleavage resulting in the cyclic structure of thiophene turning into a chain structure; finally H2S and butadiyne are formed via H migrating twice.
The haloboration of alkynes with BX3 has been calculated to proceed via a weak van der Waals complex and concerted C B/C X bond formation.
At both electrodes reduction of PhCH2X involves irreversible electron transfer concerted with breaking of the carbon halogen bond.
It is hard to imagine what might push its bond yields down other than concerted buying by the ECB, a de facto bail-out.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com