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As a result, a higher water transport rate and a higher water concentration at the anode CL can be achieved.
The limiting hydrogen concentration at the anode side due to the low stoichiometry condition can have a predominant effect on the current distribution and cell performance.
Experiments performed in binary FeCl2 electrolytes showed that the FeCl2 concentration at the anode at limiting current was equal to the saturation concentration.
It is believed that decreasing the rib width will increase hydrogen concentration at the anode side, but near zero rib width value might crush the MEA layer at high pressure contact areas which is not appropriate.
It was found that by determining the electroactive ion surface concentration at the anode with the help of impedance measurement, and by considering migration and diffusion in the bulk ion transport, the model matched the experimental results quantitatively.
Figure 6b presents the predictions of acetate concentration at the anode surface (hat{S} z_0,t)), Faradaic current (hat{I}_{{mathrm{f}}}(t)) and capacitive current (hat{I}_{mathrm{c}}(t)).
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The current distributions along the anode and cathode are presented as well as the reactant concentrations at the anode as evidence of these performance limitations.
Fuel cell performance was evaluated under various reformate compositions and operating conditions, and the CO concentrations at the anode outlet were analyzed simultaneously using on-line gas chromatography.
The developed easy to implement model using low CPU consumption predicts reasonably well the influence of current density and RH on the net water transport coefficient as well as the oxygen, hydrogen and water vapour concentrations at the anode and cathode.
However, a too thin anode GDL or a too thick cathode GDL will lower the cell performance due to the increases in the water concentration loss at the anode catalyst layer (CL) and the oxygen concentration loss at the cathode CL, respectively.
In addition, the model suggests that gas concentration effects at the anode play an important role on the global electrochemical response.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com