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As part of the alloy development program, a large complex component of the alloy (net product weight: 80 kg) was made via differential pressure casting.
In order to obtain a higher latent heat alloys, an element with higher latent heat should be selected as component of the alloy, and the mole fraction of the element should be increased.
The analysis of the experimental results by the Gibbs adsorption equation and by a statistical thermodynamic model allows the role of each component of the alloy on the interfacial energies of the system and on bonding to be determined.
These effects are shown to be caused by a nonfaradaic process of the enrichment of electrode surface by lead atoms, the latter being the surface-active component of the alloy.
For a binary melt, as the volume fraction of the solid increases the composition of the liquid is enriched in the component of the alloy that does not form the solid phase.
The majority of charge consumed on cyclic sweeping at this temperature is attributed to active dissolution of the nickel component of the alloy to form HNiO−2 (or Ni(OH −2 (or Ni(OH −3) at potentials slightly positive to the hydrogen evolution region.
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It is shown that the mechanism and kinetics of cathodic process are mainly determined by the metallic component of the alloys and anodic process is influenced by the presence of large amounts of germanium.
The cyclic voltammetry and current transients indicated more active electro chemistry of the alloy than of essentially pure Al, consistent with the expected solubility of the Fe and V components of the alloy, ac impedance analysis indicated that the underlying barrier oxide film was either absent altogether or flawed in nature.
One of them relates to the condensation of the evaporated constituents of alloy under consideration, and the finest particles (less then ~10 nm) are the oxides of the components of the alloy rather than alloy itself.
Mössbauer spectra revealed that a Sn(IV) compound and ε-Cu3Sn were components of the alloys obtained in the deposition range − 250 to − 550 mV (vs nhe).
Because of the contamination of the coolant by oxygen and followed by passivation of powder, those particles are the oxides of the components of the alloys gathered in the agglomerates rather than the metallic particles actually.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com