Exact(13)
For example, some complexes of gold(I), such as Auranofin and some related complexes have been used in the treatment of severe rheumathoidal arthritis [30].
A readily accessible route to obtain solid-supported nitrogen acyclic carbene (SNAC) complexes of gold was designed using flow chemistry, and an analogous homogeneous gold complex was synthesized for comparison.
NHC complexes of gold, platinum and palladium have been designed to elicit potent cancer cell cytotoxicity, effective anti-tumor activities in animal models as well as selective binding to molecular targets (e.g. protein thiols, DNA G-quadraplexes, mismatched DNA).
Two complexes of gold of the compositions [Au DMG ClPy] (1) and [AuCl2Py2][AuCl4] · 2[AuCl3Py] (2), where H2DMG was dimethylglyoxime, were synthesized as the products of interaction of H[AuCl4] · 4H2O with H2DMG in the presence of pyridine and characterized by X-ray structural analysis.
However, isolable CO complexes of gold in the oxidation state + iii were unknown.
Since then a number of neutral and cationic CO complexes of gold(i) have been described.
Similar(47)
The chemistry of π-complexes of gold in various oxidation states with alkenes and alkynes has recently been the subject of a very detailed and comprehensive review.
The first carbonyl complex of gold was Manchot's AuCl(CO), first reported in 1925.
Compound 61 was structurally characterised; it represents the first CO2 complex of gold in any oxidation state.
As models, we have chosen to highlight DNA/nanomaterial complexes consisting of gold nanoparticles, graphene oxides, and aptamer micelles, and we illustrate the potential of such complexes in biosensing, imaging, and medical diagnostics.
Akan states, historical complex of gold-producing forest states in western Africa lying between the Comoé and Volta rivers (in an area roughly corresponding to the coastal lands of the modern republics of Togo, Ghana, and, in part, Côte d'Ivoire).
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