The recently obtained data on structure of neutral mixed-ligand metal(I) complexes of general formula [M2[B10H10]Lx] have been generalized.
Complexes M SB) behave as bidentate oxygen donor Lewis bases to react with Ln(dik 3 Lewis acids, yielding stable heteronuclear complexes of general formula [M SB Ln(dik 3].
The structural features of the group 13 element complexes of general formula R2M O,N) and RM O,N 2 (R = alkyl, M = B, Al, Ga, In), supported by bidentate and multidentate Schiff base ligands are discussed and considered in relation to the hydrogen-bond networks.
In this contribution we provide an overview of the preparation and of the properties of different classes of luminescent dinuclear tricarbonyl rhenium(I) complexes of general formula [Re2 μ-X 2 CO 6 μ-1,2-diazine)] (X = halide, hydRe2 μ-X 2 CO 6 μ-1,2-diazine).
Dioxo-MoVI complexes of general formula Tp∗MoO2 p-SC6H4Dn Tp∗MoO2 p-SC6H4Dnp∗ = hydrotris(3,5-dimethyl-pyrazol-1-yl)borate and Dn = dendritic unit) have been synthesized and characterized by spectroscopy and mass spectrometry.
Two hexacoordinated mononuclear cobalt II thiocyanate complexes of general formula [Co LL 2 NCS 2].nH2O [LL = 2,2′-dipyridylamine (dpa), n = 1, 1; LL = N-((pyridin-2-yl benzylidene benzylamine pyridin-2-yl benzylidene benzylamine and characterized using microanalytical, spyridin-2-yl benzylidene benzylamineal results.
A series of monomeric complexes of general formula [MII(L 2 NO3 2] (MII=Cu, Co) (1), (2, 3), and [NiII(L 2(H2O)2][(NO3 2] (4) with L=malonamide have been isolated and characterized by single crystal X-ray structure.
Aiming to contribute to the design of new antitumoral drugs, we synthesized new hydrophilic Pt II) complexes of general formula [PtCl2(N,N′)] containing nitrogen bidentate amine imine and di-imine ligands derived from glucose.
A family of complexes of general formula [Co CTH)(Phendiox)]Y·solv (CTH=tetraazamacrocycle; Phendiox=catecholato or semiquinonato form of 9,10-dioxophenanthrene; Y=PF6, I, BPh4; solv=H2O, CH2Cl2, C6H5CH3) were found to undergo valence tautomeric equilibria in the solid state.
The electrochemical behaviour of fluorinated bis cyclopentadienyl) mono β-diketonato) titaniumono β-diketonatoof general formula [Cp2titaniumHCOR)]+ClO4− wIVh complexesofentadienyl and R′, R = CF3, C4H3S; CF3, C4H3O; CF3, Ph (C6H5); CF3, CH3; CH3, CH3; Ph, Ph and Ph, CH3 is described.
