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A two-step chemistry model for gaseous combustion is employed and it consists of a chain-branching reaction and a completion reaction.
Reaction was monitored on TLC, after completion reaction was quenched with methanol and solvent was evaporated under reduced pressure.
Besides, the ν (–CH2–) located at 2936, 2870 cm−1 and the ν (Si O C) located at 1101 cm−1 further prove the success of the completion reaction.
Upon completion, reaction mixture was quenched with cold water to obtain solid residue, which was washed with dilute HCl followed by water and recrystallized from ethanol.
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This work represents a large step toward creating monodisperse polymers since the dendrimers synthesized had ∼100% completion reactions for each generation, as determined by various characterization techniques.
After completion of reaction, the reaction mixture was concentrated in vacuum and dissolved in dichloromethane (CH2Cl2).
After completion of reaction, the reaction mass was quenched in ice cold water and extracted in diethyl ether.
After completion of reaction, ice water was added to the reaction mixture which resulted the precipitation of the product.
After completion of reaction, the product was precipitated by addition of water to reaction mixture.
After completion, the reaction was cooled to rt, diluted with water and extracted with EtOAc (x3).
The completion of reaction was monitored by thin layer chromatography (TLC).
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