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A series of copolymeric models were synthesized to make the complete assignment of all the signals appearing in the spectrum of the tetrapolymer.
Using a variety of triple resonance NMR experiments, complete assignment of 1H, 15N, and 13C resonances in D2 domain has been accomplished.
Well-resolved 13C NMR spectra of nylons 6, 11, 12, 66, 69, 610, and 612 dissolved in 4 1 TFE/CDCl3 allowed complete assignment of all major backbone peaks.
TOCSY and DQF-COSY experiments in combination with 13C 1H correlation measurements (HSQC, HMBC) were carried out for primary structural characterization, and a complete assignment of all 1H and 13C chemical shifts is presented.
In addition, the IP eLP2-induced structure of iloprost in solution was elucidated through a complete assignment of the 2D 1H NMR spectra for iloprost in the presence of the IP eLP2 segment.
In the current work, from a complete assignment of the IR and Raman spectra and the results obtained from the study of the VCD spectrum of the title compound, the three most stable rotamers have been detected experimentally in the liquid phase for the first time.
Similar(29)
Complete assignments of the 1H and 13C NMR spectra have been accomplished by comparison with model compounds and literature data.
The complete assignments of the vibrational spectra (IR&Raman) were made with the aid of calculated spectra both in gaseous and aqueous phases.
The complete assignments of NMR data are displayed in Tables 2.
Complete assignments of proton and carbon signals were performed by 2D NMR experiments.
However, due to the large variation of (1 JHC scalar couplings and limited chemical shift dispersion in the indirect proton dimension, it is difficult to obtain reliable and complete assignments of interfacial NOEs.
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