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Significant improvement in harvesting photo-generated currents and low series resistances were observed which lead to higher power conversion efficiencies compared to the devices without ZnO CNT.
Compared to the devices without interlayer, all the devices exhibit significant improvements of the device parameters by reducing the work function of indium tin oxide (ITO) cathode.
The devices applying CA counter electrode exhibit a lower charge-transfer resistance (1.60 Ω cm2) and larger diffusion coefficient (3.39 × 10−6 compared compared to the devices with conventional Pt counter electrode.
The devices with CsI/ZnO interlayer exhibited substantial enhancement of 800% and 12% in PCE when compared to the devices with pristine CsI and pristine ZnO as ETL, respectively.
The concept has been demonstrated in photovoltaic cells and optoelectronic devices, for which junction-type semiconductors show greatly enhanced efficiency compared to the devices consisting of a single semiconductor.
Longer matter-radiation interaction time for the photovoltaic devices with a PC-based collector results in higher absorption enhancement when compared to the devices using a slab of equivalent volume without a PC structure.
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The FM has a much smaller cross-sectional area (A) compared to the device.
Consequently, the co-sensitized DSSC (PTZ 2 + N719) gave the highest efficiency of 8.12%, exhibiting an improvement of 16.50% compared to the device sensitized with N719 alone (PCE = 6.97%) under the same conditions.
This explains the better sensitivity and faster switching of the photocurrent in the Schottky barrier devices as compared to the device with ohmic contact on both sides.
Thus, the Schottky diode shows much faster switching under pulsed UV illumination as compared to the device with ohmic contacts on both the sides.
And it has been reported that the perovskite solar cells based on Li-doped TiO2 produce higher performances compared to the device based on un-doped TiO2 [16].
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com