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Based on this study, the history of process can impact the process; besides, the achieved rate coefficient of adsorption is a function of time.
Score plots and radar fingerprints obtained respectively from principal component analysis (PCA) and fitted coefficient of adsorption isotherms for each VOC compose sufficient information to successfully discriminate different VOCs.
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The acquired rate coefficients of adsorption.
The correlation coefficients of adsorption using RHA for pseudo-second-order kinetic model are both closer to unity than those for the pseudo-first-order kinetic model.
The correlation coefficients of adsorption using rice husk and H3PO4-treated rice husk for pseudo-second-order kinetic model are both closer to unity than those for the pseudo-first-order kinetic model.
Table 9 Langmuir, Freundlich and Temkin isotherm model parameters and correlation coefficient for adsorption of As III) on MPKSF Isotherm Parameters Langmuir q max (μg g−1) 48.08 K L (L μg−1) 0.1208 R 2 0.9973 Freundlich K F 10.86 1/n 0.36 q max (μg g−1) (calculated) 54.48 R 2 0.9744 Temkin A (L g−1) 1.436 B (J mol−1) 9.72 R 2 0.9816.
Intraparticle diffusion coefficient (D p ) and the film diffusion coefficient (D f ) of adsorption process at 303 K at 1000 ppm and for CA-V-1B is Rp/m 1.8 × 10−4, the value for t 1/2/s corresponds to 335.98, D p (m2 s−1) is 2.56·10−12, and D f (m2 s−1) calculated as 3.89 × 10−11.
The high distribution coefficient (D) value of adsorption attribute to a good biosorbent.
Afterwards the coefficients of an adsorption isotherm are estimated from the low-frequency asymptotes of the FRFs and their derivatives.
From linear correlation coefficients of the adsorption isotherm, it can be said that sorption data is obeyed well, which is indicative that multilayer sorption takes place on the surface of cyanobacterial mat.
This allowed for determination of characteristic diffusion coefficients and investigation of adsorption mechanisms.
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