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The chemical effect of CO2 lowers the rates of soot inception, C2H2 addition, and PAH condensation.
Addition of CO2 lowers the pH and promotes silicate dissolution and amorphous silica, smectite and boehmite precipitation.
CO2 lowers the interfacial tension (IFT) and enhances mobility by reducing oil viscosity and causing oil swelling (Simon et al. 1978; Green and Willhite 1998).
When char was burned at 1573 K and 1673 K a faster conversion was found in N2 suggesting that the lower molecular diffusion coefficient of O2 in CO2 lowers the char conversion rate when external mass transfer influences combustion.
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