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As the CO2 amount increases, the selectivity of CH4 decreases gradually at 0.1 and 3 MPa.
CO2 amount was measured by gas chromatography (Rainbow, SP-9890, China) equipped with flame ionization detector and a packed column (GDX-502, Zhonghuida Inc., China).
The shape and size of the CO2 plume are mainly determined by the reservoir heterogeneity, well pattern and injected CO2 amount.
However, the selectivity of CO2 exhibits the opposite trend, especially when the temperature is higher than 600 °C at 0.1 MPa, the selectivity of CO2 increases significantly under the high CO2 amount.
In fact, the conversion starts at a temperature of about 600 °C, and finishes at 850 °C with a loss of 44 wt % corresponding to the stoichiometric CO2 amount in CaCO3 (Rodriguez-Navarro et al. 2009).
Because the Earth's nitrogen inventory is not lost, Lichtenegger et al. (2010) argued that these results indicate that the CO2 amount in the early N2-rich terrestrial atmosphere was at least two orders of magnitude higher than the present-time level.
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