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Those samples with OD: CO ratio ≥1 were recorded as positive.
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Open image in new window Fig. 4 Effcet of H2/CO ratio on CO methanation.
The response variables studied were: H2, CO and syngas production, H2/CO ratio, cold gas efficiency, and carbon conversion (X).
The CO conversion changes slightly as the H2/CO ratio increases.
CO selectivity over 90% with a H2/CO ratio of about 2 can be obtained at 950 °C.
Energy dispersive X-ray (EDX) spectrum of the nanocrystals (lower inset of Figure 2c) shows a Fe/Co ratio of 50 50, which is a slightly higher Co content than the Fe/Co ratio of precursors.
At the hallmark level, the ME CO ratio was 3 1, which means that relative to the ME CO ratio of 11 1 for pathways, there were more CO associations for the hallmark pairs.
Major variations in the H2/CO ratio are observed.
No obvious dependence on the Fe Co ratio is observed.
DRM results in the H2/CO ratio of unity but due to the simultaneous occurrence of RWGS, the H2/CO ratio drops below equilibrium.
Thus, comparing the H2/CO ratio for L2RhZ and L5RhZ; the H2/CO ratio of L5RhZ is consistently greater and closer to unity than L2RhZ.
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