As one of the main conclusions, it is suggested that reorganization on heating involves melting of crystals without formation of a completely relaxed and isotropic melt (at the length scale of a crystal) but a non-isotropic cluster of chain segments which turn into a more stable crystal by a fast click- but not classical secondary nucleation/growth-mechanism.
It is found that clustering of chain-ends leads to reduced crystallite strength and crystallite failure via hydrogen bond rupture and chain sliding, whereas randomly scattered defects impact the strength less and failure is by covalent bond rupture and chain scission.
Finally, the behavior of a cluster of PE chains (representing a polymer melt) interacting with the nanotube is compared to that of a single chain.
The ILS assumption suggests that all inter-particle bonds in an aggregated cluster of polymer chains and colloid particles can be represented by identical linear springs.
This cluster of nine chains has more than 90% local identity from the branch separation of CfERV 1166 towards the inner tree leaves and 78% on average from the eight innermost elements in the opposite direction towards CfERV 86 (Fig. 5B).
The α″ phase of syndiotactic polystyrene (α″sPS) is a frustrated "superstructure" that houses three triplets (three clusters of three chains, thus nine chains) in a trigonal unit-cell.
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It is closely associated with the 51 kDa subunit [ 4, 8] (NDUFV1 in H. sapiens, NUBM in Y. lipolytica, Nqo1 in T. thermophilus and NuoF in E. coli) that houses the flavin and the NADH-binding site, as well as the first cluster of the chain.
Figure 3C has the entry to cluster a set of chains with different levels of mutual similarity.
The monoclinic cell was found on the basis of our model calculations of X-ray scattering on a powder sample of this polyester, documenting that there is a clustering of side chains.
