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In the latter the negatively charged clay sheet serves as a giant immobile anion and hence has no ionic component for the conductivity.
The FTIR data reveals hydrogen bond and ionic bond interaction between functional end groups of organic modifier and surface oxygen of interlayer clay sheet lying in the organically modified clay; and, the hydrogen bond formation between intercalated polymer and organic modifier and surface oxygen of clay sheet lying in the interlayer clay gallery in the polymer clay nanocomposite.
All the previous simulations utilized periodic boundaries on the clay sheet.
In such an approach, periodic boundaries are placed on the clay sheets, thereby effectively simulating an infinite clay sheet.
In more-recent work, Fu et al. simulated the bending of a clay sheet until fracture occurred.
During intercalation, we observe the molecules diffusing toward the centre of the clay sheet in a relatively linear fashion.
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These nanocomposite hydrogels mainly consist of polymer chains connecting neighboring clay sheets (Aalaie and Rahmatpour 2008).
The remnant water molecules in the clay sheets also could influence the course of the reaction.
On further heating to 800 °C, gradual dehydroxylation of the clay sheets is evident from the structural changes.
We also calculated the angle of inclination of the alkylammonium ion between the clay sheets based on the interlayer distance d001 and the length of the alkylammonium ion.
The nano-pores and clay sheets were not observed in the SEM image of GO/clay, but obvious wrinkles, while flexible sheets were observed in the typical scanning electron microscopy images of GO.
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