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The trans isomers are much higher melting than the natural cis form.
light (300 nm < λ1 < 380 nm), CAB underwent photoisomerization from the trans to the cis form.
In its "cis" form, one of the benzene rings is tilted at 56° relative to the other one.
Moreover, the internal amide of the carbostyril unit exhibits distinctive features because of the fixed cis form of the lactam amide group.
It is found that dyes based on the D π D architecture are more amenable to isomerisation and are also more stable in the cis form when compared to D π A π D chromophores.
Shuttlecock- and bowl-equipped 4- phenylazo pyridine derivatives, which bear substituents that allow the pyridine moiety to protrude in the trans form but hinder it in the cis form, have been designed and synthesized.
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The 13-cis form has been shown to have an effect on head and neck cancers.
On irradiation at 489 nm light, 3a isomerized to give cis-form, which underwent cis-to-trans thermal isomerization in darkness at room temperature.
Here, we consider the V-shaped cis-form of the molecule [14].
Azobenzene derivatives typically prefer the trans-form over the cis-form by approximately 10 kcal mol 1.
In contrast, the cis-form azobenzene is polar and nonplanar, and it makes the duplex less stable.
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