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Electrodes with close Pt Co atomic ratios in the bulk and near surface region show grossly different electrocatalytic activities against the chemical order, the ordered L10 phase being ca. 7 times more active than the disordered fcc A1 structure.
The peaks in the figure represent the L10 structure with chemical order.
This was followed by the appearance of well-defined ω particles containing chemical order.
The decrease of the optical gap with Ga content can be correlated with the character of the chemical order of chalcogenide amorphous semiconductors.
The depth distribution of the chemical order parameter, which controls the magnetic switching mechanism of the system, has been determined by high-resolution transmission electron microscopy.
The appearance of the (001) and (110) peaks in fcc structure shows chemical order, and the splitting of the (200) and (002) peaks show the fcc to fct structure transition with a c/a < 1.
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This anomalous behavior has been explained by the role of exothermic heating accompanying chemical ordering.
Moreover, it is also found that the adsorption properties of S on Ag42Au13 can be tuned by changing its chemical ordering.
The adsorption properties of nanoalloys can be tuned not only by size and morphology, but also by composition and chemical ordering.
The as-deposited alloy was homogeneously mixed and exhibited a metastable single phase microstructure consisting of an fcc phase with short range chemical ordering of the 〈1 1/2 0〉* type.
The chemical ordering parameter S is introduced to determine the degree of chemical ordering of FePt nanoparticle films quantitatively, defined as follows [37, 38]: {mathrm{S}}^2 = left[1hbox {left(mathrm{c}/mathrm{a}right)}_{mathrm{measured}}right]/left[1hbox {left(mathrm{c}/mathrm{a}right)}_{mathrm{standard}}right] (2).
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