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In addition to constructs illustrating energy transfer, photoinduced electron transfer, charge shift reactions and proton coupled electron transfer, our review covers systems that produce proton motive force.
The decrease of interfacial tension is also observed at the electrocapillary maximum the potential of which (potential of zero charge) shift towards more positive values in the order TBA+ > THA+ > THpA+ > TOA+.
Charge shift was corrected by fixing the Zn 2p3/2 line at 1021.8 eV [14].
Charge correction was carried out in all spectra considering the charge shift of the C 1 s peak of adventitious carbon.
The C 1 s line at 285 eV has been used as a reference to rectify the charge shift of the binding energies.
An X-ray photoelectron spectrometer (XPS) was used to characterize the chemical composition and chemical bonds; the contaminated C1s (284.6 eV) was used as a reference for correcting charge shift.
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It is proposed that the point of zero charge shifts to a more positive potential, and that the oscillatory S2O2−8 reduction is governed by the Frumkin effect.
However, when the gold surface was positively charged, the apparent Gibbs free energy of adsorption exhibited a pronounced linear relationship with the surface charge, shifting to more negative values with an increase in positive electrode potential.
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