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Electrostatics charge generation by triboelectrification has significant implications for the proper design and operation of a circulating fluidized bed.
Recent studies showed feasibility of high bunch charge generation by laser-induced field emission using an array of molybdenum nanotips11,12.
Also the addition of small amount (0.5% by weight) of anti-static agent (Larostat-519) in the powder form decreases the electrostatic charge generation by altering the dynamics of particle particle and the particle wall collisions.
Recently, Colbert et al. demonstrated for PbS poly(2,3-bis 2- hexyldecyl)quinoxaline-5,8-diyl- alt- N-(2,3-bis 2- hexyldecyl[3,2,3-bis 2- hexyldecyl blends that charge generation by hole transfer from nanocrystal to polymer is less efficient than by electron transfer from polymer to nanocrystal.
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Aerosols can affect the charge generation process by two ways.
However, optimum charge generation, probed by μs-TAS, was observed in the pentyl sample showing that in the heptyl sample, due to non-agglomerated nanocrystals, the domain sizes are most presumably too small for the efficient generation of long-lived charges, which is facilitated by bigger domain sizes.
When comparing the relative effect of changing ligand length on charge generation initiated by hole transfer compared to electron transfer, it can be seen that the effect is relatively small here compared to the more significant effect on the electron transfer.
Upon photoexcitation of the nanocrystal, charge generation can occur by (III) hole transfer to the polymer.
In general, electrostatic charge generation can be classified into contact electrification (charging by repeated contact and separation of two different surfaces) and frictional electrification (charging by dynamic rubbing of two surfaces) [12].
It is pertinent to note, however, that the trend in the short circuit currents does not match the trend previously observed in the charge generation yield, as measured by μs-TAS, whereby the films made with the pentyl ligand were found to generate the highest number of charges.
This increase in charge generation yield can be explained by an increased mixing, as a more intimately mixed system results in excitons being generated closer to an interface and thus being more likely to separate into free charges before the exciton relaxes.
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