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De Santis et al. (2005) did not find any correlation between surface characteristics, fragmentation and fertilization rate, embryo quality and blastocyst formation, although there were insufficient data to evaluate the effect of shape of PB1 on the further development.
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The characteristic fragmentation implies a lack of payer monopsony.
The second characteristic fragmentation stage is the bond cleavage between C8 and C8′.
Decarboxylation is a characteristic fragmentation pathway for even-electron negative ions of carboxylic acids [32, 38].
Their daughter ions (235, 261, 249, 237) (Table 2) were the result of the characteristic fragmentation of carboxylic acids [23].
A novel dimeric conjugate, salvialeriafone (1) showed characteristic fragmentation pattern and was found to be more prone to form radical ions, as compared to monomeric diterpenoids.
Structure elucidation from the experimental data alone is very challenging; Holcapek et al. [54] have compiled characteristic fragmentation behavior for small molecules.
Further structural characterization by the LIFT MALDI-TOF/TOF method resulted in characteristic fragmentation patterns (Fig. 4b), indicating that these peptides of the two Monilinia species differ spectrally only slightly from each other and may thus be closely related.
High performance analytical instruments like quadrupole-TOF-MS or orbitrap MS offer new analytical capabilities in terms of detection sensitivity, mass accuracy, generation of characteristic fragmentation patterns, and speed.
When the [M + H]+ was selected for MS/MS analysis, the characteristic fragmentation ion at m/z 290.2483 with the chemical composition C19H31NO was detected, which could be explained by the elimination of a C8H16O2 part, namely an octanoic acid (Fig. S3, Electronic supplementary material).
Phosphopeptides display a characteristic fragmentation pattern in MS/MS analysis, commonly exhibiting a predominant ∼98 Da reduction in mass due to neutral loss of phosphoric acid [39], [28].
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